Hydrogen Chloride (HCl)

Hydrogen Chloride:

(1) HCl gas is obtained by a direct combination of H2 and Cl2 in the presence of diffused sunlight.

HCl gas is obtained by a direct combination of

(2) HCl gas is prepared in the laboratory by the action of conc. H2SO4 and NaCl.

HCl gas is prepared in the laboratory by the

(3) HCl gas is dried by conc. H2SO4 and not by CaO or P2O5 because it reacts with them.

(4) Hydrogen Chloride gas is collected by upward displacement of air, as it is heavier than air and highly soluble in water.

(5) Hydrogen Chloride gas is colorless, pungent smell, and sour taste, density of 18.25, and is highly soluble in water- demonstrated by the Fountain experiment, acidic in nature.

(6) HCl gas reacts with NH3 gas to form solid NH4Cl.

NH3 (g) + HCl (g) ———-> NH4Cl (s)

(7) When HCl gas is passed through water until no more gas is absorbed, hydrochloric acid is formed which contains about 36% HCl by weight. Thus, an aqueous solution of HCl gas is HCl acid and completely ionized.

HCl + H2O ———-> H3O+ + Cl

(8) An aqueous solution of Hydrogen Chloride containing 22.2% HCl by mass is azeotropic i.e., constant boiling mixture.

(9) HCl is a strong monobasic acid. Its acidic properties are exhibited by reactions with metals, oxides, hydroxides, carbonates, sulfites, and sulfides.

Zn + 2HCl ———-> ZnCl2 + H2
CuO + 2HCl ———-> CuCl2 + H2O
Ca(OH)2 + 2HCl ———-> CaCl2 + 2H2O
CaCO3 + 2HCl ———-> CaCl2 + H2O + CO2
Na2SO3 + 2HCl ———-> 2NaCl + SO2 + H2O
FeS + 2HCl ———-> FeCl2 + H2S

(10) With AgNO3, white ppt. of AgCl is formed which is soluble in NH4OH to form complex [Ag(NH3)2]Cl.

(11) With lead nitrate, white ppt. of PbCl2 is formed which is soluble in hot water.

(12) Aqua regia is a mixture of one part by volume of conc. HNO3 and three parts by volume of conc. HCl. It can dissolve noble metals like Pt and Au.

(13) Conc. HCl shows reducing properties as it is oxidized by strong oxidizing agents like MnO2, PbO2, Pb3O4, CaCl2, KMnO4, K2Cr2O7, etc. with the formation of metal chlorides, water, and greenish-yellow chlorine gas.

PbO2 + HCl ———-> PbCl2 + 4H2O + Cl2

(14) Hydrochloric acid is used in the manufacture of drugs, dyes, paints, glucose, etc., in the tanning industry, in the steel industry, and as a reagent.

Coordination Chemistry Definitions
Werner Theory of Coordination Compounds
Nomenclature of Coordination Compounds
Isomerism in Coordination Compounds
Bonding in Coordination Compounds
Crystal Field Theory or Ligand Field Theory
Stability of Coordination Compounds in Solution
Importance of Coordination Compounds
Organometallic Compounds
Magnetism– Tamil Board

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